S01E01 Pilot

1. Peter, Bjorn and John – “Young Folks”
- beginning montage

2. Rihanna ft Corey Gunz – “If It’s Lovin’ that You Want”
- Serena’s arrival is discussed and Blair steals Nate for sex

3. Justin Timberlake – “What Goes Around… Comes Around”
- Serena stops the Nair make-out action

4. Angels and Airwaves – “The Gift”
- Serena visits the Ostroff center; again during the ending scenes

5. Washington Social Club – “Diamond Hipster Boy”
- played during Breakfast at the Humphreys

6. Mooney Suzuki – “99%”
- played as Dan and Rufus post flyers for the concert

7. Kreesha Turner – “Bounce With Me”
- played as Jenny gives Serena an invite to the Kiss on the Lips party

8. Amy Winehouse – “Back to Black”
- played as Blair and Serena talk

9. Who Made Who – “Space for Rent”
- played as Jenny and Dan discuss Serena

10. Matthew Dear – “Send You Back”
- played as Serena and Chuck play with each other

11. Air – “Photograph”
- played during the Nate/Serena sex scene

12. Cold War Kids – “Hang Me Up to Dry”
- played as Nate tries to make up with Blair

13. The Bravery – “Time Won’t Let Me Go”
- played when Rufus and Lily talk in the gallery

14. Albert Hammond Jr. – “Hard to Live in the City”
- played as Dan meets Serena

15. Timbaland ft. Keri Hilson and D.O.E. – “The Way I Are”
- played as Chuck pervs on Jenny

16. Hanson – “Go”
- played when Serena meets Rufus

17. Akon – “Don’t Matter”
- played as Jenny follows Chuck away from the party

18. Lyrics Born – “Knock Knock”
- played as Serena and Dan look for Jenny